The effect of naturally acidified irrigation water on agricultural volcanic soils. The case of Asembagus, Java, Indonesia     

A.M.D. van Rotterdam-Los  S.P. Vriend  M.J. van Bergen  P.F.M. van Gaans   《Journal of Geochemical Exploration》2008,96(1):53-68

Acid water from the Banyuputih river (pH  3.5) is used for the irrigation of agricultural land in the Asembagus coastal area (East Java, Indonesia), with harmful consequences for rice yields. The river water has an unusual composition which is caused by seepage from the acidic Kawah Ijen crater lake into the river. This unique irrigation setting allows the study of soil acidification in situ. This paper assesses the effects of volcanogenically contaminated irrigation water on the chemical properties of the agricultural soils.The changes in soil properties were evaluated by comparing samples taken from the topsoil and sub-soil (1–3 m depth) from areas irrigated with acid water and areas irrigated with neutral water. The field survey thus resulted in four soil categories. Bulk soil composition, organic matter content, moisture content and particle size distribution were determined. Reactive phases were quantified with the selective extractions 1 M KCl, 0.1 M Na-pyrophosphate and 0.2 M acid ammonium oxalate (AAO).By comparing the four soil categories it is shown that the use of the naturally polluted irrigation water has had a large influence on the chemical composition of the topsoil. The composition of the soil solution has changed over the entire investigated soil profile. Furthermore the acid irrigation water has strongly modified the composition of the reactive phases, extracted as KCl, pyrophosphate, and AAO extractable elements, and also the bulk soil composition has been significantly modified. Overall this has resulted in the net dissolution of some elements and the net precipitation of others. The changes in the reactive phases and bulk soil composition are only apparent in the topsoil (0–20 cm) but not in the deeper soil.  相似文献   

裙带菜褐藻糖胶的分离及部分理化性质研究   总被引：1，自引：0，他引：1  

赖晓芳  沈善瑞  徐士军 《海洋技术学报》2006,25(4):58-60

以裙带菜为原材料,采用水提法从裙带菜中分离褐藻糖胶,Sevag法去蛋白,乙醇分步沉淀法进行初步纯化。结果表明裙带菜褐藻糖胶的最适提取温度为80℃,时间为8 h,加水量为1∶30,在最适条件下的提取率为1.72%,蛋白质含量为5.44%。同时本研究对部分理化性质进行了研究。结果是特性粘度为5 m pa.s,pH为8.50,含有硫酸基。  相似文献   

饱和烃经5à分子筛络合前后单体烃碳同位素分析对比研究     

杜丽  李立武  孟仟祥  房玄  丁万仁  王广 《沉积学报》2005,23(4):747-752

通过对自配标准样品(正构烷烃)进行5à分子筛吸附试验,测定了用5分子筛吸附法分离前后正构烷烃、异构烷烃和环烷烃碳同位素值,探讨试验前后碳同位素值的变化。尽管实验过程中样品经过85℃长时间加热回流及吸附样品的5à分子筛用氢氟酸酸化处理,但实验结果经仪器检测,证明该方法对正构烷烃碳同位素值影响因素不大。本文还介绍了原油和煤可溶有机质中饱和烃络合前后的单体烃碳同位素分析方法。并在前人工作的基础上,改进采用微型索氏抽提加热回流实验装置,既提高了样品的回收率,也减少了样品中轻组分的损失。  相似文献   

A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples     

Helko Borsdorf  Petra Fiedler  Dorit Wilke  Holger Weiß 《洁净——土壤、空气、水》2003,31(1):19-24

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.  相似文献   

利用SPOT和ETM+影像进行县级土地利用调查--以河北省万全县为例   总被引：7，自引：0，他引：7  

朱运海 江涛曹银璇  张运生 《四川测绘》2004,27(1):26-29

本文以SPOT和ETM 影像作为主要信息源，经过对图像进行几何纠正、配准、增强和融合等一系列处理后，在ARCVIEW GIS基础上，成功完成了对河北省万全县土地资源利用情况的调查分析。同时还对应用遥感技术成功获取土地资源利用信息的方法和技术进行了探讨。  相似文献   

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux     

Zakaria Boujamlaoui  Thierry Bariac  Philippe Biron  Laurent Canale  Patricia Richard 《Comptes Rendus Geoscience》2005,337(6):589-598

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).  相似文献   

卤水提锂的萃取体系概述   总被引：9，自引：1，他引：9       下载免费PDF全文

张金才  王敏  戴静 《盐湖研究》2005,13(1):42-49

介绍了国内外萃取法在含锂溶液,尤其在卤水中提取锂的部分研究进展情况,重点对各种萃取体系的机理和特点进行了说明,并对今后我国盐湖卤水萃取法提锂研究的方向进行了总结。  相似文献   

Application of AMD to the Determination of Cropprotection Agents in Drinking Water. Part III: Solid Phase Extraction and Affecting Factors Anwendung der AMD-Technik zur Bestimmung von Pflanzenbehandlungsmittel-Wirkstoffen im Trinkwasser. Teil III: Festphasenextraktion und ihre Einflußfaktoren     

G. Pfaab  H. Jork 《洁净——土壤、空气、水》1994,22(5):216-223

The more sensitive an analysis method the more care must be given to sample preparation. Solid phase extraction (SPE) onto RP 18 phases has established itself as a general purification and enrichment technique for trace components in aqueous samples. Various factors may thereby influence the recovery rate. For example, the ratio amount of sorbent and sample volume should be taken into account to avoid breakthrough of the investigated substance. Extracting phenylurea herbicides from drinking water, the ratio should be 1 g RP 18 sorbent per 1 L water sample. Concerning the flow rate for the fungicides procymidone, vinclozolin, and iprodione, the recovery rate decreases using higher flow rates than 3 or 6 mL/min. In the case of phenylurea herbicides, a flow rate of 10 or 14 mL/min showed best results. Even the coefficient of variation is below ± 5% at these flow rates. Furthermore, the company dependence should be considered because the recovery rate might differ by up to 40% using the nominally identical material. The same applies to the batch dependence of quality from the same company. The concentration of the eluate must also be monitored and carried out with great care to avoid decreasing the recovery rate. Considering these factors of influence, SPE is a very useful tool in sample preparation, particularly if an automated system is used.  相似文献   

遥感影像信息在澳门、磨刀门海域工程建设中的应用及其效益     

罗丹  陈学廉 《遥感学报》1993,(3)

本文介绍了计算机处理和光学处理相结合的信息提取方法并得到显著效益。根据澳门海域和磨刀门海域工程建设中的实际需要,成功地运用遥感影像信息为澳门海域工程物理模型试验提供了模型水流流态与原型水流流态相似性的验证,为磨刀门海域围垦工程提供了水下潜坝的动态影像信息,并取得了较好的社会效益和经济效益。  相似文献   

浅海水下地形地貌遥感信息提取与应用     

李铁芳  易建春  厉银喜  迟耀斌  苏民生  宋宗贤 《遥感学报》1991,(1)

本文根据笔者在我国渤海海峡、闽江口、瓯江口以及珠江口附近海域的遥感实验,讨论由卫星遥感提供的水下地形地貌信息的特征、机理,提出使用信息论和灰色系统论方法分析水深遥感信息传递的过程。以此为依据,建立水深信息提取模型,研究其实用性、精度和效果。实践表明,水深遥感的测量精度没有达到大、中比例尺常规测量的要求。但作为大面积、短周期的宏观分析,特别是遥感图像上显示的海水表层流场特征,对判别浅海水下地形走向和地貌单元,了解其冲刷、沉积作用的动力因素,动态变化等具有十分重要的意义,它成为常规方法的补充手段。对近海的规划、开发,如港湾海水养殖、航道选址、海上工程、海水排污等方面的海水环境分析与宏观评价及监测,具有一定的优势。本文着重讨论了以下三个问题: 1.水下地形地貌遥感的原理与信息特性;2.水深信息提取及灰色系统方法与模糊判别模型分析;3.遥感水下地形地貌的应用与效果分析。  相似文献